HuagongsheHuagongshe Chemistry Print Report · For research reference only
Dodecanedial → Cyclopentadeca-2,14-dien-1-one
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Dodecanedial | HCID 5743459 | — |
| Reactant | 1,3-Bis(dimethylphosphono)propan-2-one | HCID 13512255 | — |
| Reactant | 15-(Dimethylphosphono)-pentadec-12-en-14-on-1-al | HCID 54214484 | — |
| Solvent | tert-Butanol | HCID 6386 | — |
| Product | Cyclopentadeca-2,14-dien-1-one | HCID 53676690 | 26% |
Reaction Steps
The above reaction was repeated, but 15-(dimethylphosphono)-pentadec-12-en-14-on-1-al was replaced by a mixture of 0.79 g (4 mMole) of dodecan-1,12-dial and 1.10 g (4 mMole) of 1,3-bis(dimethylphosphono)-propan-2-one in 10 ml of 90% t-butanol. Identical introduction time and work up gave 229 mg (26%) of cyclopentadeca-2,14-dien-1-one in a similar ratio of isomers
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04302607 |
| Source dataset | uspto-grants-1981_11 |
| ORD ID | ord-4cca4c4ed9ce49e5bb3fb4f1673397d5 |
| Source note | uspto-grants-1981_11 |