HuagongsheHuagongshe Chemistry Print Report · For research reference only
Cyclopentadeca-2,14-dien-1-one → Cyclopentadecanone
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Cyclopentadeca-2,14-dien-1-one | HCID 53676690 | — |
| Reactant | HCID 178418361 | HCID 178418361 | — |
| Catalyst | Palladium | HCID 23938 | — |
| Solvent | Ethanol | HCID 702 | — |
| Product | Cyclopentadecanone | HCID 10409 | 94% |
Reaction Steps
A solution of 1.00 g (4.55 mMole) of cyclopentadeca-2,14-dien-1-one in 20 ml of ethanol was hydrogenated in the presence of 50 mg of palladium on charcoal. Hydrogen uptake (230 ml) was complete after 1 h at 20°. The mixture was filtered, evaporated and distilled to give 0.96 g (94%) of EXALTONE® having b.p. 115°/0.1 Torr; m.p. 65°-66°.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04302607 |
| Source dataset | uspto-grants-1981_11 |
| ORD ID | ord-8a47ffa9d62f4fc1b26be9920027bb5f |
| Source note | uspto-grants-1981_11 |