HuagongsheHuagongshe Chemistry Print Report · For research reference only
Benzoyl chloride → Stilbene
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Benzoyl chloride | HCID 7412 | — |
| Reactant | Styrene | HCID 7501 | — |
| Reactant | N,N-Dimethylbenzylamine | HCID 7681 | — |
| Catalyst | palladium(II) acetate | HCID 167845 | — |
| Solvent | P-Xylene | HCID 7809 | — |
| Product | Stilbene | HCID 11502 | 72.6% |
Reaction Steps
1.12 ml (0.005 millimol) of palladium acetate, 7.04 g (50 millimols) of benzoyl chloride, 5.22 g (50 millimols) of styrene and 6.76 g (50 millimols) of N-benzyldimethylamine in 100 ml of p-xylene are stirred for 11.5 hours at 130° C. 6.54 g (63% of theory) of stilbene are obtained. This corresponds to 6,300 mols of stilbene per mol of catalyst.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04335055 |
| Source dataset | uspto-grants-1982_06 |
| ORD ID | ord-a4efb30737f4415ea207a25590d0202e |
| Source note | uspto-grants-1982_06 |