Ammonia → HCID 86738422, compound

HRID 1156265Notes

Reaction equation

HRID 1156265 reaction equation
[O:1]=[C:2]([C:14]1[O:18][C:17](/[CH:19]=[CH:20]/[C:21]([OH:23])=[O:22])=[CH:16][CH:15]=1)[CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH2:12][CH3:13].[NH3:24]>CCOCC>[O:1]=[C:2]([C:14]1[O:18][C:17](/[CH:19]=[CH:20]/[C:21]([O-:23])=[O:22])=[CH:16][CH:15]=1)[CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH2:12][CH3:13].[NH4+:24]

Participants

4

Reactant 2

HCID 222AmmoniaHCID 12851998HCID 12851998, compound

Product 1

HCID 86738422HCID 86738422, compound

Reagents, catalysts & solvents 1

HCID 3283Diethyl EtherSolvent

Procedure

A mixture of 5.0 g (0.0156 mole) of (E)-3-[5-(1-oxododecyl)-2-furanyl]-2-propenoic acid and 200 ml of anhydrous ether is stirred at room temperature. The above mixture is saturated with ammonia gas and allowed to stand at room temperature overnight. The solid precipitate is separated by filtration and washed with ether to give ammonium (E)-3-[5-(1-oxododecyl)-2-furanyl]-2-propenoate.

Workup

  1. customThe solid precipitate is separated by filtration
  2. washwashed with ether

Sources & evidence

ORD record
ord-0333c253a190499d98e17b15d9dae7f6
Source dataset
uspto-grants-1982_06
Patent number
US04335098

Reaction notes

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