HuagongsheHuagongshe Chemistry Print Report · For research reference only
Carbon Tetrachloride → 2-CHLORO-1-(m-NITROPHENYLSULFONYL)ETHYL PHENYL SULFIDE
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Carbon Tetrachloride | HCID 5943 | — |
| Reactant | Benzenesulfenyl chloride | HCID 11008040 | — |
| Reactant | HCID 20535994 | HCID 20535994 | — |
| Solvent | Acetic Acid | HCID 176 | — |
| Product | 2-CHLORO-1-(m-NITROPHENYLSULFONYL)ETHYL PHENYL SULFIDE | HCID 13044796 | — |
Reaction Steps
In a mixture of 50 ml of glacial acetic acid and 100 ml of carbon tetrachloride at 56° was dissolved 30.9 g (0.145 mole) of m-nitrophenyl vinyl sulfone. Addition of 21.0 g (0.145 mole) of benzenesulfenyl chloride produced an exotherm to 58°. The clear solution was allowed to stand for seventy hours. Removal of the solvent by evaporation at reduced pressure and recrystallization of the residue from toluene gave yellow needles, m.p. 125.5°-126.5°.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04335142 |
| Source dataset | uspto-grants-1982_06 |
| ORD ID | ord-d86eb5f1d56041bca1589d18bb349d69 |
| Source note | uspto-grants-1982_06 |