HuagongsheHuagongshe Chemistry Print Report · For research reference only
Carbon Tetrachloride → 2-CHLORO-1-(p-TOLYLSULFONYL)ETHYL p-BROMOPHENYL SULFIDE
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Carbon Tetrachloride | HCID 5943 | — |
| Reactant | P-Tolyl vinyl sulfone | HCID 79665 | — |
| Reactant | Benzenesulfenyl chloride, 4-bromo- | HCID 11746248 | — |
| Product | 2-CHLORO-1-(p-TOLYLSULFONYL)ETHYL p-BROMOPHENYL SULFIDE | HCID 13044797 | — |
Reaction Steps
A solution of 26.8 g (0.147 mole) of p-tolyl vinyl sulfone in 50 ml of carbon tetrachloride was treated with 32.8 g (0.146 mole) of p-bromobenzenesulfenyl chloride. There was an exotherm from 25° to 29° in one hour. The mixture was allowed to stand 72 hours. The solvent was removed at reduced pressure and the residue recrystallized from ethyl acetate-petroleum ether (1:1) to give colorless needles, m.p. 82.5°-84.0°.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04335142 |
| Source dataset | uspto-grants-1982_06 |
| ORD ID | ord-eb26364a24b944e88812e0b7138a17b5 |
| Source note | uspto-grants-1982_06 |