HuagongsheHuagongshe Chemistry Print Report · For research reference only
Sulfur dichloride → 2-CHLORO-1-(PHENYLSULFONYL)ETHYL p-t-BUTYLPHENYL SULFIDE
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Sulfur dichloride | HCID 25353 | — |
| Reactant | Phenyl vinyl sulfone | HCID 79664 | — |
| Reactant | p-t-Butylbenzenesulfenyl chloride | HCID 12801136 | — |
| Solvent | Acetic Acid | HCID 176 | — |
| Solvent | Carbon Tetrachloride | HCID 5943 | — |
| Product | 2-CHLORO-1-(PHENYLSULFONYL)ETHYL p-t-BUTYLPHENYL SULFIDE | HCID 13044802 | 52% |
Reaction Steps
A solution of 25.2 g (0.150 mole) of phenyl vinyl sulfone in 100 ml of carbon tetrachloride and 30 ml of glacial acetic acid was treated with 30.1 g (0.150 mole) of p-t-butylbenzenesulfenyl chloride. There was an exotherm of 2° within 10 minutes. The red color of the sulfenyl chloride disappeared within 24 hours. Evaporation of the solvent left 54 g (98%) of crude product m.p. 58°-69°. Recrystallization from 100 ml of ethyl acetate-petroleum ether (1:1) gave 29 g (52%) of colorless crystals, m.p. 67°-69°.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04335142 |
| Source dataset | uspto-grants-1982_06 |
| ORD ID | ord-c31442d7eb4c43d5abc99325f356301f |
| Source note | uspto-grants-1982_06 |