HuagongsheHuagongshe Chemistry Print Report · For research reference only
Carbon Tetrachloride → 2-CHLORO-1-(p-CHLOROPHENYLSULFONYL)ETHYL p-t-BUTYLPHENYL SULFIDE
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Carbon Tetrachloride | HCID 5943 | — |
| Reactant | 1-Chloro-4-(ethenylsulfonyl)benzene | HCID 21703 | — |
| Reactant | p-t-Butylbenzenesulfenyl chloride | HCID 12801136 | — |
| Product | 2-CHLORO-1-(p-CHLOROPHENYLSULFONYL)ETHYL p-t-BUTYLPHENYL SULFIDE | HCID 13044807 | 61% |
Reaction Steps
To a solution of 26.1 g (0.129 mole) of p-chlorophenyl vinyl sulfone in 100 ml of carbon tetrachloride at 25° C. was added 25.9 (0.129 mole) of p-t-butylbenzenesulfenyl chloride. The reaction mixture was allowed to stand for six days in a closed flask. Removal of the solvent by evaporation gave 55 g (106%) of crude product, m.p. 52°-68°. Recrystallization from 300 ml ethylacetatepentane (1:5) gave 31.5 g (61%) of pure product, m.p. 65°-67°.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04335142 |
| Source dataset | uspto-grants-1982_06 |
| ORD ID | ord-16d52b57d617400cb477ad3e7de31bb6 |
| Source note | uspto-grants-1982_06 |