HuagongsheHuagongshe Chemistry Print Report · For research reference only
Triethylamine → p-t-BUTYLPHENYL 1-(p-CHLOROPHENYL SULFONYL)VINYL SULFIDE
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Triethylamine | HCID 8471 | — |
| Reactant | 2-CHLORO-1-(p-CHLOROPHENYLSULFONYL)ETHYL p-t-BUTYLPHENYL SULFIDE | HCID 13044807 | — |
| Solvent | Tetrahydrofuran | HCID 8028 | — |
| Product | p-t-BUTYLPHENYL 1-(p-CHLOROPHENYL SULFONYL)VINYL SULFIDE | HCID 13044814 | 84% |
Reaction Steps
p-t-Butylphenyl 1-(p-chlorophenylsulfonyl)-2-chloroethyl sulfide (16.12 g, 40.0 mmoles) was dissolved in 80 ml of tetrahydrofuran at 25° C. The solution was treated with 5.6 ml (4.08 g, 40.3 mmoles) of triethylamine and allowed to stand for 30 minutes. After filtration had separated the triethylamine hydrochloride, the filtrate was freed of solvent by evaporation at reduced pressure. The residue was a colorless solid, m.p. 74°-79°. Recrystallization from 25 ml of ethanol gave 12.2 g (84%) of pure product m.p. 79°-81°.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04335142 |
| Source dataset | uspto-grants-1982_06 |
| ORD ID | ord-bf7c901da0f84cb4bcd5d486d4c4cc82 |
| Source note | uspto-grants-1982_06 |