Acrylonitrile → HCID 54377318, compound

HRID 1156453Notes

Reaction equation

HRID 1156453 reaction equation
[CH:1]([C:3]1[CH:11]=[CH:10][C:6]([C:7](Cl)=[O:8])=[CH:5][CH:4]=1)=O.[C:12](#[N:15])[CH:13]=C>>[CH:7]([C:6]1[CH:10]=[CH:11][C:3]([CH:1]=[CH:13][C:12]#[N:15])=[CH:4][CH:5]=1)=[O:8]

Participants

3

Reactant 2

HCID 7855AcrylonitrileHCID 124246204-Formylbenzoyl chloride

Product 1

HCID 54377318HCID 54377318, compoundYield 44.6%

Procedure

The procedure described in Example 28 is repeated, except that 8.23 g (0.05 mol) of 4-formylbenzoyl chloride and 3.32 g (0.0625 mol) of acrylonitrile are used. After a reaction time of 3 hours at 120° C., 3.5 g (0.0223 mol) of 4-formylcinnamonitrile are obtained, corresponding to a yield of 44.6% of theory; melting point 122° C. Analysis for C10H7NO (molecular weight 157): calculated C 76.22%, H 4.49%, N 8.91%, found C 76.30%, H 4.55%, N 8.96%.

Sources & evidence

ORD record
ord-77e73e27a6294c30b9313798a0d2177d
Source dataset
uspto-grants-1982_06
Patent number
US04335054

Reaction notes

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