HuagongsheHuagongshe Chemistry Print Report · For research reference only
Ethyl Acrylate → HCID 3346402, compound
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Ethyl Acrylate | HCID 8821 | — |
| Reactant | Diisopropylethylamine | HCID 81531 | — |
| Reactant | 3,5-Dimethoxybenzoyl chloride | HCID 87003 | — |
| Catalyst | HCID 178514132 | HCID 178514132 | — |
| Solvent | Benzonitrile | HCID 7505 | — |
| Product | HCID 3346402 | HCID 3346402 | 49.4% |
Reaction Steps
0.0792 g (5 millimols) of palladium(II) cyanide, 10.03 g (50 millimols) of 3,5-dimethoxybenzoyl chloride, 6.26 g (62.5 millimols) of ethyl acrylate and 6.46 g (50 millimols) of N-ethyldiisopropylamine, in 100 ml of benzonitrile, are stirred for 70 minutes at 140° C. The crude product is distilled in vacuo. Working up affords 5.83 g (49% of theory) of ethyl 3,5-dimethoxycinnamate as a colourless liquid.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04335054 |
| Source dataset | uspto-grants-1982_06 |
| ORD ID | ord-83097b7052414567906a93f5e23dff74 |
| Source note | uspto-grants-1982_06 |