HCID 13023225, compound → HCID 20534344, compound

HRID 1156983Notes

Reaction equation

HRID 1156983 reaction equation
[CH3:1][O:2][C:3]1[CH:4]=[C:5]([C:9]23[CH2:17][CH2:16][CH2:15][CH:14]2[C:13](=O)[N:12]([CH2:19][C:20]2[CH:25]=[CH:24][CH:23]=[CH:22][CH:21]=2)[C:11](=O)[CH2:10]3)[CH:6]=[CH:7][CH:8]=1.[H-].[Al+3].[Li+].[H-].[H-].[H-]>>[CH3:1][O:2][C:3]1[CH:4]=[C:5]([C:9]23[CH2:17][CH2:16][CH2:15][CH:14]2[CH2:13][N:12]([CH2:19][C:20]2[CH:21]=[CH:22][CH:23]=[CH:24][CH:25]=2)[CH2:11][CH2:10]3)[CH:6]=[CH:7][CH:8]=1

Participants

3

Reactant 2

HCID 13023225HCID 13023225, compoundHCID 21226445Aluminium lithium hydride

Product 1

HCID 20534344HCID 20534344, compound

Procedure

Following the procedure set forth in Example 19, 4a-(3-methoxyphenyl)-2-benzyl-2,3,4,4a,5,6,7,7a-octahydro-1,3-dioxo-1H-2-pyrindine was reduced by reaction with lithium aluminum hydride to provide 4a-(3-methoxyphenyl)-2-benzyl-2,3,4,4a,5,6,7,7a-octahydro-1H-2-pyrindine.

Sources & evidence

ORD record
ord-51a44279d3c3431ebea4dd318a0fc8a9
Source dataset
uspto-grants-1982_06
Patent number
US04337341

Reaction notes

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