methyl [(5,6-dichloro-9a-ethyl-3-oxo-1,2,9,9a-tetrahydro-3H-fluoren-7-yl)oxy]acetate → HCID 20520851, compound

HRID 1157044Notes

Reaction equation

HRID 1157044 reaction equation
ClC1C(Cl)=C(OCC(OC)=O)C=C2C=1C1C(CC)(C2)CCC(=O)C=1.[CH2:25]([C:28]12[CH2:40][CH2:39][C:38](=[O:41])[CH:37]=[C:36]1[C:35]1[C:30](=[CH:31][C:32]([O:44][CH2:45][C:46]([O:48]CC)=[O:47])=[C:33]([Cl:43])[C:34]=1[Cl:42])[CH2:29]2)[CH:26]=[CH2:27]>>[CH2:25]([C:28]12[CH2:40][CH2:39][C:38](=[O:41])[CH:37]=[C:36]1[C:35]1[C:30](=[CH:31][C:32]([O:44][CH2:45][C:46]([OH:48])=[O:47])=[C:33]([Cl:43])[C:34]=1[Cl:42])[CH2:29]2)[CH:26]=[CH2:27]

Participants

3

Reactant 2

HCID 12806942methyl [(5,6-dichloro-9a-ethyl-3-oxo-1,2,9,9a-tetrahydro-3H-fluoren-7-yl)oxy]acetateHCID 86738257ethyl [(9a-allyl-5,6-dichloro-3-oxo-1,2,9,9a-tetrahydro-3H-fluoren-7-yl)oxy]acetate

Product 1

HCID 20520851HCID 20520851, compound

Procedure

Carrying out a reaction as described in Example 20, Step D, except that the methyl [(5,6-dichloro-9a-ethyl-3-oxo-1,2,9,9a-tetrahydro-3H-fluoren-7-yl)oxy]acetate is replaced by an equimolar quantity of ethyl [(9a-allyl-5,6-dichloro-3-oxo-1,2,9,9a-tetrahydro-3-H-fluoren-7-yl)oxy]acetate, there is obtained [(9a-allyl-5,6-dichloro-3-oxo-1,2,9,9a-tetrahydro-3H-fluoren-7-yl)oxy]acetic acid.

Workup

  1. customCarrying out a reaction

Sources & evidence

ORD record
ord-0cb2b3300de64c1cbc017996db2a814c
Source dataset
uspto-grants-1982_06
Patent number
US04337354

Reaction notes

Loading…