HCID 20534502, compound → HCID 13613310, compound

HRID 1157046Notes

Reaction equation

HRID 1157046 reaction equation
ClC1C(Cl)=C(CC([O-])=O)C=C2C=1C1C(CC)(C2)CCC(=O)C=1.[Cl:23][C:24]1[C:36]([Cl:37])=[C:35]([O:38][CH2:39][C:40]([O:42]C(C)(C)C)=[O:41])[CH:34]=[C:33]2[C:25]=1[C:26]1[C:31]([CH2:47][CH2:48][CH3:49])([CH2:32]2)[CH2:30][CH2:29][C:28](=[O:50])[CH:27]=1>>[Cl:23][C:24]1[C:36]([Cl:37])=[C:35]([O:38][CH2:39][C:40]([OH:42])=[O:41])[CH:34]=[C:33]2[C:25]=1[C:26]1[C:31]([CH2:47][CH2:48][CH3:49])([CH2:32]2)[CH2:30][CH2:29][C:28](=[O:50])[CH:27]=1

Participants

3

Reactant 2

HCID 20534502HCID 20534502, compoundHCID 86738259HCID 86738259, compound

Product 1

HCID 13613310HCID 13613310, compound

Procedure

Carrying out a reaction as described in Example 53, Step B, except that the tert.-butyl [(5,6-dichloro-9a-ethyl-3-oxo-1,2,9,9a-tetrahydro-3H-fluoren-7-yl)acetate is replaced by an equimolar amount of tert.-butyl [(5,6-dichloro-3-oxo-9a-propyl-1,2,9,9a-tetrahydro-3H-fluoren-7-yl)oxy]-acetate, thereby is obtained [(5,6-dichloro-3-oxo-9a-propyl-1,2,9,9a-tetrahydro-3H-fluoren-7-yl)oxy]acetic acid.

Workup

  1. customCarrying out a reaction

Sources & evidence

ORD record
ord-8e51ca6eec454fd7bf27feb9cc22b6b8
Source dataset
uspto-grants-1982_06
Patent number
US04337354

Reaction notes

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