反应详情

First, 3.71 g of 4,4′-difluorobenzil and 1.71 g of o-phenylenediamine were stirred on heating in a solvent (200 mL of chloroform) for 6 hours. The reaction solution was cooled to room temperature, washed with HCl (1N) and a saturated aqueous solution of sodium chloride, and dried with magnesium sulfate. The solvent was removed to obtain a ligand HFdpq (2,3-bis(4-fluorophenyl) quinoxaline) (pale yellow powder, yield: 99%).

1. washwashed with HCl (1N)
2. dry with materiala saturated aqueous solution of sodium chloride, and dried with magnesium sulfate
3. customThe solvent was removed