HCID 11386113, compound → dodecafluoronaphthacene

HRID 1160037Notes

Reaction equation

HRID 1160037 reaction equation
[F:1][C:2]1[C:19]2[C:18](F)([F:20])[C:17]3[C:16](F)([F:22])[C:15]4[C:10](=[C:11]([F:27])[C:12]([F:26])=[C:13]([F:25])[C:14]=4[F:24])[C:9](F)([F:28])[C:8]=3[C:7](F)([F:30])[C:6]=2[C:5]([F:32])=[C:4]([F:33])[C:3]=1[F:34].FC1C2C(F)(F)C3C(=C(F)C4C(C=3F)=C(F)C(F)=C(F)C=4F)C(F)(F)C=2C(F)=C(F)C=1F>>[F:20][C:18]1[C:17]2[C:8]([C:7]([F:30])=[C:6]3[C:19]=1[C:2]([F:1])=[C:3]([F:34])[C:4]([F:33])=[C:5]3[F:32])=[C:9]([F:28])[C:10]1[C:15](=[C:14]([F:24])[C:13]([F:25])=[C:12]([F:26])[C:11]=1[F:27])[C:16]=2[F:22]

Participants

3

Reactant 2

HCID 11386113HCID 11386113, compoundHCID 11455169HCID 11455169, compound

Product 1

HCID 11247765dodecafluoronaphthacene

Procedure

compounds (8) and/or (9) are/is reacted with a reducing agent so as to obtain compound (10). That is, as shown in scheme 6, 1,2,3,4,5,5,6,6,7,8,9,10,11,11,12,12-hexadecafluoro-5,6,11,12-tetrahydronaphthacene (8) is reacted with a reducing agent so that it is partially defluoridated so as to obtain dodecafluoronaphthacene (10). Also, s shown in scheme 7, 1,2,3,4,5,5,6,7,8,9,10,11,12,12-tetradecafluoro-5,12-dihydronaphthacene (9) is reacted with a reducing agent so that it is partially defluoridated so as to obtain dodecafluoronaphthacene (10).

Sources & evidence

ORD record
ord-68ce69446b164de58de003584c0d5294
Source dataset
uspto-grants-2010_10
Patent number
US07816172B2

Reaction notes

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