Benzoic acid, 3-mercapto- → 3-Sulfanylbenzonitrile

HRID 1160245Notes

Reaction equation

HRID 1160245 reaction equation
[C:1]([C:3]1[CH:4]=[C:5]([S:9](Cl)(=O)=O)[CH:6]=[CH:7][CH:8]=1)#[N:2].SC1C=C(C=CC=1)C(O)=O>>[SH:9][C:5]1[CH:4]=[C:3]([CH:8]=[CH:7][CH:6]=1)[C:1]#[N:2]

Participants

3

Reactant 2

HCID 95737Benzoic acid, 3-mercapto-HCID 28013603-Cyanobenzene-1-sulfonyl chloride

Product 1

HCID 147953343-Sulfanylbenzonitrile

Procedure

The required 3-Mercapto-benzonitrile is prepared from 3-Cyano-benzenesulfonyl chloride following the procedure for the preparation of 3-Mercaptobenzoic acid described in Journal of Heterocyclic Chemistry (1982), 19(4), 961-5.

Sources & evidence

ORD record
ord-97621bc47df943dda3068976cdd92578
Source dataset
uspto-grants-2010_10
Patent number
US07816389B2

Reaction notes

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