HCID 68692152, compound → HCID 68687596, compound

HRID 1160383Notes

Reaction equation

HRID 1160383 reaction equation
[N+:1]([C:4]1[CH:9]=[CH:8][CH:7]=[CH:6][C:5]=1[CH2:10][CH2:11][CH2:12][CH2:13][CH2:14][C:15]1[CH:24]=[CH:23][CH:22]=[CH:21][C:16]=1[C:17]([O:19][CH3:20])=[O:18])([O-])=O>[Pd].CO>[NH2:1][C:4]1[CH:9]=[CH:8][CH:7]=[CH:6][C:5]=1[CH2:10][CH2:11][CH2:12][CH2:13][CH2:14][C:15]1[CH:24]=[CH:23][CH:22]=[CH:21][C:16]=1[C:17]([O:19][CH3:20])=[O:18]

Participants

4

Reactant 1

HCID 68692152HCID 68692152, compound

Product 1

HCID 68687596HCID 68687596, compound

Reagents, catalysts & solvents 2

HCID 23938PalladiumCatalystHCID 887MethanolSolvent

Conditions

Temperature
70 °C

Procedure

36 g (0.11 M) of methyl 2-[5-(2-nitrophenyl)pentyl]benzoate and 4 g of palladium-on-charcoal are added to 400 ml of methanol in a 1000 ml stainless-steel autoclave. The reaction medium is then stirred under hydrogen pressure (10 bar) at 70° C. for 3 hours.

Sources & evidence

ORD record
ord-1e67a68764ea48718dc19216b5807f23
Source dataset
uspto-grants-2010_10
Patent number
US07816397B2

Reaction notes

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