HuagongsheHuagongshe Chemistry Print Report · For research reference only
Benzoyl Peroxide → Methyl 2-(bromomethyl)benzoate
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Benzoyl Peroxide | HCID 7187 | — |
| Reactant | Methyl o-toluate | HCID 33094 | — |
| Reactant | N-bromobutanimide | HCID 67184 | — |
| Solvent | Carbon Tetrachloride | HCID 5943 | — |
| Product | Methyl 2-(bromomethyl)benzoate | HCID 2734813 | — |
Reaction Steps
2-bromomethyl-benzoic acid methyl ester (Dvornikovs, V.; Smithrud, D. B.; J. Org. Chem.; 2002, 67, 2160-2167) was prepared, via the cited literature preparation, from methyl 2-methylbenzoate by alpha-bromination (NBS, benzoyl peroxide, CCl4, 80° C.).
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US07820704B2 |
| Source dataset | uspto-grants-2010_10 |
| ORD ID | ord-c0b418cbb1f14f89b7192aca0d4b4038 |
| Source note | uspto-grants-2010_10 |