Potassium Hydroxide → HCID 57276899, compound

HRID 1163992Notes

Reaction equation

HRID 1163992 reaction equation
[CH3:1][O:2][C:3]1[C:8]([CH2:9][CH:10]=[CH2:11])=[CH:7][CH:6]=[CH:5][C:4]=1[O:12][C:13]1[CH:18]=[CH:17][CH:16]=[CH:15][C:14]=1[Cl:19].[OH-].[K+]>CO>[CH3:1][O:2][C:3]1[C:8]([CH:9]=[CH:10][CH3:11])=[CH:7][CH:6]=[CH:5][C:4]=1[O:12][C:13]1[CH:18]=[CH:17][CH:16]=[CH:15][C:14]=1[Cl:19]

Participants

4

Reactant 2

HCID 14797Potassium HydroxideHCID 13066664HCID 13066664, compound

Product 1

HCID 57276899HCID 57276899, compoundYield 90.2%

Reagents, catalysts & solvents 1

HCID 887MethanolSolvent

Procedure

2-Chlorophenyl 2-methoxy-3-allylphenyl ether (21.50 g) was added to methanol (100 ml) saturated with potassium hydroxide, and the mixture was treated in a similar manner to that of Example 3-(2) and recrystallized from methanol to give colorless crystals of 2-chlorophenyl 2-methoxy-3-(1-propenyl)phenyl ether (19.40 g). mp 61°-62° C.

Workup

  1. additionthe mixture was treated in a similar manner to that of Example 3-(2)
  2. customrecrystallized from methanol

Sources & evidence

ORD record
ord-98a4ef4e0a9944c3bbfb1e95b5bb1550
Source dataset
uspto-grants-1983_01
Patent number
US04367238

Reaction notes

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