Dimethyl Sulfate → HCID 20513477, compound

HRID 1164016Notes

Reaction equation

HRID 1164016 reaction equation
[CH2:1]([C:4]1[CH:9]=[CH:8][CH:7]=[C:6]([O:10][C:11]2[CH:16]=[CH:15][CH:14]=[CH:13][C:12]=2[CH3:17])[C:5]=1[OH:18])[CH:2]=[CH2:3].S(OC)(O[CH3:23])(=O)=O.[OH-].[K+]>O>[CH3:23][O:18][C:5]1[C:4]([CH2:1][CH:2]=[CH2:3])=[CH:9][CH:8]=[CH:7][C:6]=1[O:10][C:11]1[C:12]([CH3:17])=[CH:13][CH:14]=[CH:15][CH:16]=1

Participants

5

Reactant 3

HCID 6497Dimethyl SulfateHCID 14797Potassium HydroxideHCID 13066659HCID 13066659, compound

Product 1

HCID 20513477HCID 20513477, compound

Reagents, catalysts & solvents 1

HCID 962WaterSolvent

Procedure

2-Allyl-6-(o-tolyloxy)phenol (80 g), dimethyl sulfate (63 ml), potassium hydroxide (56 g) and water (200 ml) were treated in a similar manner to that of Example 4-(1) to give oily o-tolyl 2-methoxy-3-allylphenyl ether (78.6 g). bp 120°-135° C./0.7 mmHg.

Sources & evidence

ORD record
ord-79e37d6dde39421285ca16e5cd1f3093
Source dataset
uspto-grants-1983_01
Patent number
US04367238

Reaction notes

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