Thionyl Chloride → HCID 20513455, compound

HRID 1164069Notes

Reaction equation

HRID 1164069 reaction equation
[CH3:1][O:2][C:3]1[CH:10]=[CH:9][C:8]([O:11][C:12]2[CH:17]=[CH:16][CH:15]=[CH:14][C:13]=2[Cl:18])=[CH:7][C:4]=1[CH2:5]O.S(Cl)([Cl:21])=O>N1C=CC=CC=1.C1C=CC=CC=1>[Cl:21][CH2:5][C:4]1[CH:7]=[C:8]([O:11][C:12]2[CH:17]=[CH:16][CH:15]=[CH:14][C:13]=2[Cl:18])[CH:9]=[CH:10][C:3]=1[O:2][CH3:1]

Participants

5

Reactant 2

HCID 24386Thionyl ChlorideHCID 54496987HCID 54496987, compound

Product 1

HCID 20513455HCID 20513455, compound

Reagents, catalysts & solvents 2

HCID 1049PyridineCatalystHCID 241BenzeneSolvent

Procedure

A mixture of 2-methoxy-5-(2-chlorophenoxy)benzyl alcohol (8 g), thionyl chloride (4.4 ml) and pyridine (3 drops) in dried benzene (60 ml) was treated in a similar manner to that of Example 3-(6) to give oily 2-chlorophenyl 3-chloromethyl-4-methoxyphenyl ether (8.5 g).

Workup

  1. additionwas treated in a similar manner to that of Example 3-(6)

Sources & evidence

ORD record
ord-fb2e3a74cbfe41129d6a4368a564d1b8
Source dataset
uspto-grants-1983_01
Patent number
US04367238

Reaction notes

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