Water → HCID 20512577, compound

HRID 1164164Notes

Reaction equation

HRID 1164164 reaction equation
C([O:8][C:9]1[CH:26]=[CH:25][C:12]([O:13][C:14]2[N:15]=[N+:16]([O-:24])[C:17]3[CH:23]=[CH:22][CH:21]=[CH:20][C:18]=3[N:19]=2)=[CH:11][CH:10]=1)C1C=CC=CC=1.O.C(Cl)[Cl:29]>>[OH:8][C:9]1[CH:26]=[CH:25][C:12]([O:13][C:14]2[N:15]=[N+:16]([O-:24])[C:17]3[CH:23]=[C:22]([Cl:29])[CH:21]=[CH:20][C:18]=3[N:19]=2)=[CH:11][CH:10]=1

Participants

4

Reactant 3

HCID 962WaterHCID 6344Dichloromethane3×HCID 20512584HCID 20512584, compound

Product 1

HCID 20512577HCID 20512577, compound

Procedure

A solution of 0.05 mole borontribromide in 100 cc methylene chloride is added, dropwise, to a well stirred cold (-62°) solution of 3-(4-benzyloxyphenoxy)-1,2,4-benzotriazine-1-oxide (0.05 mole) in 400 cc methylene chloride. When the addition is complete, the temperature of the reaction is allowed to rise slowly to room temperature. The reaction mixture is then poured into 1 liter of water and an additional 500 cc of methylene chloride is added. The mixture is stirred vigorously for 40 minutes and the insoluble solid is filtered.

Workup

  1. additionWhen the addition
  2. customto rise slowly to room temperature
  3. filtrationthe insoluble solid is filtered

Sources & evidence

ORD record
ord-b1d3b3a8613b44f2bcbe2f9ef44e6558
Source dataset
uspto-grants-1983_01
Patent number
US04368068

Reaction notes

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