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HuagongsheHuagongshe Chemistry Print Report · For research reference only
HRID 1164658Generated: November 2, 2026

Benzyl Bromide → 1-Benzyl-2-(benzylsulfanyl)pyridin-1-ium bromide

https://huagongshe.com/reaction/1164658

Reaction equation

Participants

RoleNameHCIDCharge
ReactantBenzyl BromideHCID 7498—
Reactant2-benzylsulfanylpyridineHCID 472961—
SolventDiethyl EtherHCID 3283—
Product1-Benzyl-2-(benzylsulfanyl)pyridin-1-ium bromideHCID 1343500159.2%

Reaction Steps

A mixture of 2-(benzylthio)pyridine (2.01 g) and benzyl bromide (1.71 g) was kept at ambient temperature for 4 days. Trituration at length with ether gave a solid which was removed by filtration and dried to give the title compound (2.2 g) mp 125°-7° C. (Found: C, 61.6; H, 5.2; N, 3.6%. C19H18BrNS requires C, 61.3; H, 4.9; N, 3.8%).

Provenance & Evidence

DOI10.6084/m9.figshare.5104873.v1
Patent numberUS04370477
Source datasetuspto-grants-1983_01
ORD IDord-ace65a15cf0243488cff966f27013764
Source noteuspto-grants-1983_01