HRID1164690

反应详情

EQUATION

反应方程式

REACTANTS

反应物

HCID3044917

Benzene, 1,1'-tellurinylbis(4-methoxy-

C14H14O3Te

结构：CC(C)CCC[C@@H](C)[C@H]1CC[C@H]2[C@@H]3CC=C4C[C@@H](O)CC[C@]4(C)[C@H]3CC[C@]12C.O=C([O-])C=S

HCID86738763

未命名化合物

PRODUCTS

生成物

结构：CC(=O)[O-].CC(C)CCC[C@@H](C)[C@H]1CC[C@H]2[C@@H]3CC=C4C[C@@H](O)CC[C@]4(C)[C@H]3CC[C@]12C

HCID86738762

未命名化合物

收率 100%

PROCEDURE

实验过程

5-Cholesten-3β-ol-thionoacetate (111 mg, 0.25 mmol), was reacted with bis-(p-methoxyphenyl)-telluroxide for 0.25 h. 5-Cholesten-3β-ol-acetate (107 mg, 100%) was obtained after P.l.c. (petroleum ether-ethyl acetate 9:1. The product obtained was recrystallized from acetone (90 mg, 84%), m.p. 113°-114° (lit., 114°-115°).

来源与证据

来源类型: Open Reaction Database
ORD 记录: ord-6d8aa0ddc6964191966a5adb4e7f156e
来源数据集: uspto-grants-1983_01
DOI: 10.6084/m9.figshare.5104873.v1
专利: US04370497
来源说明: uspto-grants-1983_01

反应 SMILES

[CH3:1][CH:2]([CH2:4][CH2:5][CH2:6][C@H:7]([C@@H:9]1[C@:26]2([CH3:27])[C@H:12]([C@H:13]3[C@H:23]([CH2:24][CH2:25]2)[C@:21]2([CH3:22])[C:16]([CH2:17][C@@H:18]([OH:28])[CH2:19][CH2:20]2)=[CH:15][CH2:14]3)[CH2:11][CH2:10]1)[CH3:8])[CH3:3].S=[CH:30][C:31]([O-:33])=[O:32].COC1C=CC([Te](C2C=CC(OC)=CC=2)=O)=CC=1>>[CH3:3][CH:2]([CH2:4][CH2:5][CH2:6][C@H:7]([C@@H:9]1[C@:26]2([CH3:27])[C@H:12]([C@H:13]3[C@H:23]([CH2:24][CH2:25]2)[C@:21]2([CH3:22])[C:16]([CH2:17][C@@H:18]([OH:28])[CH2:19][CH2:20]2)=[CH:15][CH2:14]3)[CH2:11][CH2:10]1)[CH3:8])[CH3:1].[C:31]([O-:33])(=[O:32])[CH3:30]