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HRID1164692

反应详情

EQUATION

反应方程式

HRID 1164692 的结构方程式

REACTANTS

反应物

2
结构：COc1ccc([Te](=O)c2ccc(OC)cc2)cc1
HCID3044917

Benzene, 1,1'-tellurinylbis(4-methoxy-

C14H14O3Te

结构：CC(C)CCC[C@@H](C)[C@H]1CC[C@H]2[C@@H]3CC=C4C[C@@H](O)CC[C@]4(C)[C@H]3CC[C@]12C.O=C([O-])C1C=CC=CC1=S
HCID86738767

未命名化合物

PRODUCTS

生成物

1
结构：CC(C)CCC[C@@H](C)[C@H]1CC[C@H]2[C@@H]3CC=C4C[C@@H](O)CC[C@]4(C)[C@H]3CC[C@]12C.O=C([O-])c1ccccc1
HCID86738766

未命名化合物

收率 66%

PROCEDURE

实验过程

5-Cholesten-3β-ol-thionobenzoate (253 mg, 0.50 mmol) was reacted with bis-(p-methoxyphenyl)-telluroxide for 1.5 h. 5-Cholesten-3β-ol-benzoate (162 mg, 66%) m.p. 143°-145° was obtained after p.l.c. (petroleum ether-ethyl acetate 9:1). The product obtained was recrystallized from ethyl acetate (130 mg, 53%), m.p. 144.5 (lit., 150°-151°), νmax (CCl4) 1722 cm-1.