HuagongsheHuagongshe Chemistry Print Report · For research reference only
N-Phenylhydroxylamine → Nitrosobenzene
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | N-Phenylhydroxylamine | HCID 7518 | — |
| Reactant | Bis(p-methoxyphenyl) telluroxide | HCID 3044917 | — |
| Solvent | Chloroform | HCID 6212 | — |
| Product | Nitrosobenzene | HCID 11473 | 90% |
| Product | Benzene, 1,1'-tellurobis[4-methoxy- | HCID 4605422 | 88% |
Reaction Steps
Phenylhydroxylamine (109 mg, 1 mmol) and bis-(p-methoxyphenyl)-telluroxide (376 mg, 1.05 mmol) were stirred in chloroform (4 ml) at room temperature under nitrogen for 0.1 h. Evaporation of the solvent and column chromatography (petroleum ether-ethyl acetate 9:1) gave bis-(p-methoxyphenyl)-telluride (150 mg, 88%) and nitrosobenzene (96 mg, 90%) m.p. 66°-68°).
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04370497 |
| Source dataset | uspto-grants-1983_01 |
| ORD ID | ord-8c48d2137ddb4b98b98fab7680aeb140 |
| Source note | uspto-grants-1983_01 |