HuagongsheHuagongshe Chemistry Print Report · For research reference only
HCID 54418173, compound → HCID 14541463, compound
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | HCID 54418173 | HCID 54418173 | — |
| Reactant | HCID 178418287 | HCID 178418287 | — |
| Solvent | Dichloromethane | HCID 6344 | — |
| Product | HCID 14541463 | HCID 14541463 | — |
Reaction Steps
A solution of 11.8 g of ethyl 1-tert-butoxycarbonyl-4-(2-hydroxyethyl)-piperidine-2-carboxylate and 12.6 g of pyridinium chlorochromate in 175 ml methylene chloride is stirred under nitrogen at room temperature for 80 minutes. Mixture is filtered and purified by flash chromatography using ethyl acetate/hexane (25:75) to yield 1-(tert-butoxycarbonyl)-2-ethoxycarbonyl-piperidine-4-acetaldehyde.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04906621 |
| Source dataset | uspto-grants-1990_03 |
| ORD ID | ord-7b9e2f5ab0624c6397bf46539430c758 |
| Source note | uspto-grants-1990_03 |