HuagongsheHuagongshe Chemistry Print Report · For research reference only
1-Tris(methylthio)methyl acenaphthene → Methyl 1-acenaphthenecarboxylate
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | 1-Tris(methylthio)methyl acenaphthene | HCID 14799775 | — |
| Reactant | Methanol--water (1/1) | HCID 22242641 | — |
| Catalyst | Mercuric Chloride | HCID 24085 | — |
| Catalyst | Mercuric oxide | HCID 30856 | — |
| Product | Methyl 1-acenaphthenecarboxylate | HCID 14799776 | — |
Reaction Steps
1-Tris(methylthio)methyl acenaphthene (18.4 g), Mercury (II) Chloride (68 g) and Mercury (II) Oxide (22 g) were slurried in MeOH/H2O, 12/1 (1500 ml), stirred at room temperature for 18 hours, then refluxed for two hours, and then allowed to cool.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04906655 |
| Source dataset | uspto-grants-1990_03 |
| ORD ID | ord-bba8d7c3a1424b7ebcb0777c1da92232 |
| Source note | uspto-grants-1990_03 |