HuagongsheHuagongshe Chemistry Print Report · For research reference only
HCID 244245, compound → 4-(4'-Dimethylaminophenyl)-2-(4'-chlorophenyl)-6-phenylpyridine
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | HCID 244245 | HCID 244245 | — |
| Reactant | Ammonium Acetate | HCID 517165 | — |
| Reactant | 1-(2-Oxo-2-phenylethyl)pyridin-1-ium bromide | HCID 2798954 | — |
| Solvent | Acetic Acid | HCID 176 | — |
| Product | 4-(4'-Dimethylaminophenyl)-2-(4'-chlorophenyl)-6-phenylpyridine | HCID 19862912 | — |
Reaction Steps
13.9 parts of 1-phenacylpyridinium bromide and 14.27 parts of 1-(4-chlorophenyl)-3-(4-dimethylaminophenyl)-1-oxoprop-2-ene are heated at 120° C. for 3.5 hours together with 34 parts of ammonium acetate in 50 parts of glacial acetic acid. Working up as described in Example 1 gives 4-(4'-dimethylaminophenyl)-2-(4'-chlorophenyl)-6-phenylpyridine in the form of a colorless powder, which dissolves in glacial acetic acid to give a yellow color (λmax: 425 nm).
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04908447 |
| Source dataset | uspto-grants-1990_03 |
| ORD ID | ord-9f63b47a3c524ff8b48d7b91cb03638b |
| Source note | uspto-grants-1990_03 |