HCID 19862949, compound → HCID 14716215, compound

Participants

Reaction Steps

This example was carried out as illustrated in Example 4 with lithium aluminum hydride (6.14 g, 0.162 mole), titanium (IV) chloride (7.67 g, 4.43 mL, 0.041 mole) and 4,5-dichloro-4,5-difluoro-2-pentafluoroethyl-2-trifluoromethyl-1,3-dioxolane (29.5 g, 0.081 mole) in tetrahydrofuran (100 mL). The pure desired product obtained after distillation and washing with ice-water, perfluoro-2-ethyl-2-methyl-1,3-dioxole, was 9.0 g (38% yield); boiling point 42°-43° C.

Provenance & Evidence