Sodium Hydroxide → N,N'-Bis(2-hydroxyethyl)-2-nitro-p-phenylenediamine

HRID 1165610Notes

Reaction equation

HRID 1165610 reaction equation
[OH:1][CH2:2][CH2:3][NH:4][C:5]1[CH:10]=[CH:9][C:8]([N:11]2[C:15](=O)[CH2:14][O:13][CH-]2)=[CH:7][C:6]=1[N+:17]([O-:19])=[O:18].[OH-].[Na+]>C(O)C>[OH:1][CH2:2][CH2:3][NH:4][C:5]1[CH:10]=[CH:9][C:8]([NH:11][CH2:15][CH2:14][OH:13])=[CH:7][C:6]=1[N+:17]([O-:19])=[O:18]

Participants

4

Reactant 2

HCID 14798Sodium HydroxideHCID 178516900HCID 178516900, compound

Product 1

HCID 5488740N,N'-Bis(2-hydroxyethyl)-2-nitro-p-phenylenediamineYield 90%

Reagents, catalysts & solvents 1

HCID 702EthanolSolvent

Procedure

0.2 mole (53.4 g) of N-[4-(β-hydroxyethyl)amino-3-nitrophenyl]oxazolidone, prepared according to Example 5, is treated with 135 ml of 3N sodium hydroxide to which 55 ml of 96° strength ethanol has been added. 0.18 mole (44.2 g) of the expected product is obtained. It melts at 107° C.

Workup

  1. additionhas been added

Sources & evidence

ORD record
ord-3d524d3bd5304a3f83c9340f03f8eac1
Source dataset
uspto-grants-1990_03
Patent number
US04910341

Reaction notes

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