Benzo(b)naphtho(1,2-d)thiophene, 10-methyl- → HCID 20065910, compound

HRID 1165671Notes

Reaction equation

HRID 1165671 reaction equation
[Br:1]CC1C2C(C=CC=1)=CC1C3C=CC=CC=3OC=1C=2.[CH3:20][C:21]1[CH:37]=[CH:36][C:24]2[S:25][C:26]3[CH:35]=[CH:34][C:33]4[CH:32]=[CH:31][CH:30]=[CH:29][C:28]=4[C:27]=3[C:23]=2[CH:22]=1>C(Cl)Cl>[Br:1][CH2:20][C:21]1[CH:37]=[CH:36][C:24]2[S:25][C:26]3[CH:35]=[CH:34][C:33]4[CH:32]=[CH:31][CH:30]=[CH:29][C:28]=4[C:27]=3[C:23]=2[CH:22]=1

Participants

4

Reactant 2

HCID 150076Benzo(b)naphtho(1,2-d)thiophene, 10-methyl-HCID 14770215HCID 14770215, compound

Product 1

HCID 20065910HCID 20065910, compoundYield 39%

Reagents, catalysts & solvents 1

HCID 6344DichloromethaneSolvent

Procedure

Using the procedure outlined in 6A, 10-methyl-benzo[b]naphtho[1,2-d]thiophene (H. G. Pars Pharmaceutical Laboratories, Inc.) gave a 39.0% yield of 10-(bromomethyl)-benzo[b]naphtho[1,2-d]thiophene, mp 202°-203°, (CH2Cl2), (C,H,Br,S).

Sources & evidence

ORD record
ord-d178ba972158481ea113f7b8e39ab2fc
Source dataset
uspto-grants-1990_03
Patent number
US04910218

Reaction notes

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