Fumaric Acid → HCID 21954893, compound

HRID 1165772Notes

Reaction equation

HRID 1165772 reaction equation
[C:1]([OH:8])(=[O:7])/[CH:2]=[CH:3]/[C:4]([OH:6])=[O:5]>CC(C)=O>[OH2:5].[C:1]([OH:8])(=[O:7])/[CH:2]=[CH:3]/[C:4]([OH:6])=[O:5]

Participants

3

Reactant 1

HCID 444972Fumaric Acid

Product 1

HCID 21954893HCID 21954893, compoundYield 785%

Reagents, catalysts & solvents 1

HCID 180AcetoneSolvent

Procedure

The above base, 1.3 g (0.0019 mol), in acetone was treated with 0.215 g (0.0019 mol) of fumaric acid. The crystals were separated to afford 1.0 g (65%) of the (E)-2-butenedioate monohydrate, of isomer "A", mp 150°-151°, [α]D25 -58.52° (C 0.972, MeOH).

Workup

  1. customThe crystals were separated

Sources & evidence

ORD record
ord-82ce4995af7349f69ba5c8cfbf642db4
Source dataset
uspto-grants-1990_03
Patent number
US04912102

Reaction notes

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