HuagongsheHuagongshe Chemistry Print Report · For research reference only
2-Bromopyridine → 4-(4-Methylpyrimidin-2-YL)benzaldehyde
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | 2-Bromopyridine | HCID 7973 | — |
| Reactant | 4-Formylphenylboronic Acid | HCID 591073 | — |
| Reactant | 3-Formylphenylboronic acid | HCID 2734356 | — |
| Reactant | 2-Bromo-4-methylpyrimidine | HCID 10942928 | — |
| Product | 4-(4-Methylpyrimidin-2-YL)benzaldehyde | HCID 22630861 | — |
Reaction Steps
The title compound was prepared by a procedure analogous to Reference Example 12 by substituting 4-formylphenylboronic acid and 2-bromo-4-methylpyrimidine (prepared as described in Helv. Chim. Acta 1992, 75, 1621) for the 3-formylphenylboronic acid and 2-bromopyridine, respectively, of Reference Example 12. MS 199 (M+H)+.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US06613747B2 |
| Source dataset | uspto-grants-2003_09 |
| ORD ID | ord-92676adcd14743c6bb791e311fd8ce20 |
| Source note | uspto-grants-2003_09 |