HuagongsheHuagongshe Chemistry Print Report · For research reference only
Stannous chloride dihydrate → (4-Bromo-5-chloro-2-methoxyphenyl)hydrazine
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Stannous chloride dihydrate | HCID 61436 | — |
| Reactant | 4-Bromo-5-chloro-2-methoxyaniline | HCID 22997667 | — |
| Reactant | Sodium Nitrite | HCID 23668193 | — |
| Product | (4-Bromo-5-chloro-2-methoxyphenyl)hydrazine | HCID 22997648 | 73% |
Reaction Steps
The title compound was prepared by the general procedure described above for Preparations 2a-i using 4-chloro-5-bromo-2-aminoanisole (7.68 g), NaNO2 (2.25 g), and SnCl2.2H2O (15 g). Workup gave 5.5 g (73%) of (4-bromo-5-chloro-2-methoxyphenyl)hydrazine which was used in the next step without further purification.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US06613786B2 |
| Source dataset | uspto-grants-2003_09 |
| ORD ID | ord-55de0e9ade104b95bc6d561470a61ffe |
| Source note | uspto-grants-2003_09 |