Stannous chloride dihydrate → HCID 22997602, compound

Participants

Reaction Steps

The title compound was prepared by the general procedure described above for Preparations 2a-i using 4-fluoro-2-aminoanisole (14.11 g), NaNO2 (7.59 g) and SnCl2.2H2O (49.64 g). Workup gave 4.9 g (31%) of (5-fluoro-2-methoxyphenyl)hydrazine. MS (M−H)+: 157.00; 1H NMR (300 MHz, CDCl3) δ6.71 (1H, dd, J=10.5, 3.0 Hz), 6.32 (1H, dd, J=7.5, 4.9 Hz), 6.38 (1H, dt, J=8.4, 3.0 Hz), 3.78 (3H, s).

Provenance & Evidence