1-Iodohexane → HCID 22218311, compound

HRID 1166683Notes

Reaction equation

[Br:1][C:2]1[C:3]([OH:17])=[CH:4][C:5]2[C:6]([CH3:16])([CH3:15])[CH2:7][CH:8]=[C:9]([CH:12]([CH3:14])[CH3:13])[C:10]=2[CH:11]=1.I[CH2:19][CH2:20][CH2:21][CH2:22][CH2:23][CH3:24]>>[Br:1][C:2]1[CH:11]=[C:10]2[C:5](=[CH:4][C:3]=1[O:17][CH2:19][CH2:20][CH2:21][CH2:22][CH2:23][CH3:24])[C:6]([CH3:15])([CH3:16])[CH2:7][CH:8]=[C:9]2[CH:12]([CH3:13])[CH3:14]

Participants

Reactant 2

HCID 125271-Iodohexane

HCID 22218215HCID 22218215, compound2×

Product 1

HCID 22218311HCID 22218311, compoundYield 39%

Procedure

Following General Procedure O, 3-bromo-5-isopropyl-8,8-dimethyl-7,8-dihydronaphthalen-2-ol (Compound 97, 0.11 g, 0.37 mmol) was reacted with 1-iodohexane to afford 0.058 g (39%) of the title compound as a clear oil.

Sources & evidence

ORD record: ord-3df7d36f04854cb0b00afc0b35685e6e
Source dataset: uspto-grants-2003_09
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US06613917B1

Reaction notes

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