HuagongsheHuagongshe Chemistry Print Report · For research reference only
2-[4-(2-Ethoxycarbonylvinyl)naphthyl]dioxolane → 2-[4-(2-Ethoxycarbonylethyl)naphthyl]dioxolane
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | 2-[4-(2-Ethoxycarbonylvinyl)naphthyl]dioxolane | HCID 53682933 | — |
| Catalyst | Palladium | HCID 23938 | — |
| Solvent | Ethyl Acetate | HCID 8857 | — |
| Product | 2-[4-(2-Ethoxycarbonylethyl)naphthyl]dioxolane | HCID 54530694 | 98% |
Reaction Steps
To a solution of 2-[4-(2-ethoxycarbonylvinyl)naphthyl]dioxolane (701 mg, 2.35 mmol) in ethyl acetate (15 mL) was added palladium (5% on BaCO3, 51 mg). The mixture was stirred under a hydrogen atmosphere for 16 hr, filtered by suction through Celite and concentrated to provide 689 mg (98%) of a colorless oil.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US06613942B1 |
| Source dataset | uspto-grants-2003_09 |
| ORD ID | ord-7f176542c60f46da9c62d93a4287629c |
| Source note | uspto-grants-2003_09 |