Hydroxide → HCID 22995147, compound

HRID 1167040Notes

Reaction equation

HRID 1167040 reaction equation
[I-].[CH2:2]([N+:6]1([CH:11]2[CH2:18][CH2:17][CH2:16][CH2:15][CH2:14][CH2:13][CH2:12]2)[CH2:10][CH2:9][CH2:8][CH2:7]1)[CH2:3][CH2:4][CH3:5].[OH-:19]>O>[OH-:19].[CH2:2]([N+:6]1([CH:11]2[CH2:18][CH2:17][CH2:16][CH2:15][CH2:14][CH2:13][CH2:12]2)[CH2:10][CH2:9][CH2:8][CH2:7]1)[CH2:3][CH2:4][CH3:5]

Participants

4

Reactant 2

HCID 961HydroxideHCID 22995133HCID 22995133, compound

Product 1

HCID 22995147HCID 22995147, compound

Reagents, catalysts & solvents 1

HCID 962WaterSolvent

Procedure

N-butyl-N-cyclooctylpyrrolidinium iodide salt (95 gms., 0.26 mole) is dissolved in 300 ml. water in a 1000 ml. plastic bottle. To the solution, 300 gms. of Ion Exchange Resin OH (BIO RAD® AG1-X8) is added and the mixture is stirred at room temperature overnight. The mixture is filtered and the solids rinsed with an additional 250 ml. of water. The original mixture is filtered and the rinses are combined and a small amount is titrated with 0.1N HCl to indicate the presence of 0.24 mol hydroxide (0.24 mol N-butyl-N-cyclooctylpyrrolidinium hydroxide) in the solution.

Workup

  1. additionof Ion Exchange Resin OH (BIO RAD® AG1-X8) is added
  2. filtrationThe mixture is filtered
  3. washthe solids rinsed with an additional 250 ml
  4. filtrationThe original mixture is filtered

Sources & evidence

ORD record
ord-bbae94fe73aa4f26a2d78430e29ebcb4
Source dataset
uspto-grants-2003_09
Patent number
US06616911B2

Reaction notes

Loading…