HuagongsheHuagongshe Chemistry Print Report · For research reference only
Ethyl Acetate → HCID 22993710, compound
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Ethyl Acetate | HCID 8857 | — |
| Reactant | dimethyl furan-3,4-dicarboxylate | HCID 303461 | — |
| Reactant | HCID 178418361 | HCID 178418361 | — |
| Catalyst | Rhodium | HCID 23948 | — |
| Solvent | Methanol | HCID 887 | — |
| Product | HCID 22993710 | HCID 22993710 | 100% |
Reaction Steps
Dimethyl 3,4-furandicarboxylate (5.20 g, 28.0 mmol) was combined with 5% Rhodium/C in methanol (30 mL) and ethyl acetate (10 mL) in a Parr shaker bottle. The reaction was charged to 50 psi hydrogen and was shaken for 8.5 h. The reaction was filtered over celite, concentrated in vacuo to give the dimethyl 3,4-tetrahydrofuran dicarboxylate (5.2 g, 100%) as an oil MS (M−CH3OH)+=156.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US06620823B2 |
| Source dataset | uspto-grants-2003_09 |
| ORD ID | ord-aadcb005d49e4a66a8b059231910b2b0 |
| Source note | uspto-grants-2003_09 |