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HuagongsheHuagongshe Chemistry Print Report · For research reference only
HRID 1167997Generated: November 1, 2026

Ethanol → Gamma-Butyrolactone

https://huagongshe.com/reaction/1167997

Reaction equation

Participants

RoleNameHCIDCharge
ReactantEthanolHCID 702—
ReactantMaleic AnhydrideHCID 7923—
Solvent1-PropanolHCID 1031—
ProductGamma-ButyrolactoneHCID 7302—
Product1,4-ButanediolHCID 8064—

Reaction Steps

In the case when the C4+ hydrogenation feedstock is the crude maleic anhydride stream, then the light impurities are also hydrogenated in the hydrogenation step and result in light hydrogenation products including ethanol and propanol, which can be removed from the hydrogenation product as an overhead product by distillation. Heavy impurities and heavy impurity hydrogenation products can be separated by conventional distillation techniques as a bottom product from the crude hydrogenation product. Maleic anhydride derivatives, such as maleic acid and fumaric acid, are hydrogenated to form a corresponding additional amount of butane-1,4-diol, γ-butyrolactone, and tetrahydrofuran.

Provenance & Evidence

DOI10.6084/m9.figshare.5104873.v1
Patent numberUS06620949B1
Source datasetuspto-grants-2003_09
ORD IDord-1b88affa25e843c4841528c5f1c3b885
Source noteuspto-grants-2003_09