Potassium Iodide → HCID 22326085, compound

HRID 1168120Notes

Reaction equation

HRID 1168120 reaction equation
S([O-])([O-])(=O)=O.C(C1C=CC([I+:17]C2C=CC(C(CC)(C)C)=CC=2)=CC=1)(CC)(C)C.[C:29]([C:34]1[CH:39]=[CH:38][C:37]([I+:40][C:41]2[CH:46]=[CH:45][C:44]([C:47]([CH2:50][CH3:51])([CH3:49])[CH3:48])=[CH:43][CH:42]=2)=[CH:36][CH:35]=1)([CH2:32][CH3:33])([CH3:31])[CH3:30].[I-].[K+]>>[I-:17].[C:47]([C:44]1[CH:45]=[CH:46][C:41]([I+:40][C:37]2[CH:38]=[CH:39][C:34]([C:29]([CH2:32][CH3:33])([CH3:31])[CH3:30])=[CH:35][CH:36]=2)=[CH:42][CH:43]=1)([CH2:50][CH3:51])([CH3:49])[CH3:48]

Participants

3

Reactant 2

HCID 4875Potassium IodideHCID 71350713Bis{bis[4-(2-methylbutan-2-yl)phenyl]iodanium} sulfate

Product 1

HCID 22326085HCID 22326085, compound

Procedure

While being cooled with ice, 500 ml of water was added to the reaction liquid that had been stirred for 10 hours at room temperature, and a component dissolved in the reaction liquid was extracted with dichloromethane. The dichloromethane-containing organic phase was washed with aqueous sodium hydrogencarbonate and then with water. After being thus washed, the organic phase was concentrated to obtain di(4-t-amylphenyl)iodonium sulfate. The sulfate was put into an excess amount of aqueous potassium iodide. The resulting aqueous solution was extracted with dichloromethane and washed with water, and this organic phase was concentrated to obtain di(4-t-amylphenyl)iodonium iodide. The yield was 75 g.

Workup

  1. extractionThe resulting aqueous solution was extracted with dichloromethane
  2. washwashed with water
  3. concentrationthis organic phase was concentrated

Sources & evidence

ORD record
ord-3f3741e0b77a41c08eecddfbb5473cb6
Source dataset
uspto-grants-2003_09
Patent number
US06623910B2

Reaction notes

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