Chlorodi(isopropyl)silane → HCID 123816274, compound

HRID 1169563Notes

Reaction equation

HRID 1169563 reaction equation
[CH2:1]([SiH:5]([CH:9]([CH3:11])[CH3:10])[CH:6]([CH3:8])[CH3:7])[CH:2]([CH3:4])C.C([SiH](C(C)C)Cl)(C)C>>[CH:1]1([SiH:5]([CH:6]([CH3:7])[CH3:8])[CH:9]([CH3:10])[CH3:11])[CH2:2][CH2:4]1

Participants

3

Reactant 2

HCID 2758383Chlorodi(isopropyl)silaneHCID 123811283HCID 123811283, compound

Product 1

HCID 123816274HCID 123816274, compound

Procedure

The procedure of synthesizing Compound 40a was repeated, except that diisopropylchlorosilane (4.10 mL, 96.0 mmol) and cyclopropylmagnesium bromide THF solution (1.0M, 100 mL) were employed, whereby the Compound 44a was obtained as a colorless liquid (boiling point; 35 mmHg, 86 to 89° C. fraction, 1.84 g, 50%).

Sources & evidence

ORD record
ord-844775fd74eb46848986d4a150b8bd07
Source dataset
uspto-grants-2010_11
Patent number
US07825103B2

Reaction notes

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