1-Bromo-3-methylbutane → (3-Methylbutyl)diisopropylsilane

HRID 1169566Notes

Reaction equation

HRID 1169566 reaction equation
[CH:1]([SiH:4]([CH:10]([CH3:12])[CH3:11])CC(C)(C)C)([CH3:3])[CH3:2].Br[CH2:14][CH2:15][CH:16]([CH3:18])[CH3:17]>>[CH3:17][CH:16]([CH3:18])[CH2:15][CH2:14][SiH:4]([CH:10]([CH3:12])[CH3:11])[CH:1]([CH3:3])[CH3:2]

Participants

3

Reactant 2

HCID 78911-Bromo-3-methylbutaneHCID 123529220Diisopropyl(2,2-dimethylpropyl)silane

Product 1

HCID 123187826(3-Methylbutyl)diisopropylsilane

Procedure

The procedure of synthesizing Compound 51a was repeated, except that 1-bromo-3-methylbutane (12.6 mL, 100 mmol) was employed, whereby the Compound 53a was obtained as a colorless liquid (12.6 g, 73%).

Sources & evidence

ORD record
ord-04122c5af7d14a4aaaf94575c9ab43ee
Source dataset
uspto-grants-2010_11
Patent number
US07825103B2

Reaction notes

Loading…