HuagongsheHuagongshe Chemistry Print Report · For research reference only
HRID 1171439Generated: October 25, 2026
2,3-Dihydroxybutanedioate → (2-Heptyloxy-4-iodophenyl)methanol
https://huagongshe.com/reaction/1171439
Participants
| Role | Name | HCID | Charge |
|---|
| Reactant | 2,3-Dihydroxybutanedioate | HCID 3806114 | — |
| Reactant | Sodium | HCID 5360545 | — |
| Reactant | Potassium | HCID 5462222 | — |
| Reactant | Diisobutylaluminumhydride | HCID 21225700 | — |
| Reactant | Methyl 2-heptyloxy-4-iodobenzene | HCID 68767162 | — |
| Solvent | Toluene | HCID 1140 | — |
| Product | (2-Heptyloxy-4-iodophenyl)methanol | HCID 68768142 | — |
Reaction Steps
87.5 ml of a solution of diisobutylaluminum hydride (DiBAlH) is added at 0° C. to a solution of methyl 2-heptyloxy-4-iodobenzene (14 g, 43.7 mmol) previously obtained, in toluene (450 ml). The solution is stirred for 2 hours at 0° C., and then a saturated solution of mixed tartrate of sodium and potassium is added.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|
| Patent number | US07829588B2 |
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| Source dataset | uspto-grants-2010_11 |
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| ORD ID | ord-e3e2253e0740417b80bbdee44e4ecb96 |
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| Source note | uspto-grants-2010_11 |
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