Toluene → 2,3,5-Triiodobenzoic acid
Reaction equation
[CH:1]1[C:6]([I:7])=[C:5]([I:8])[C:4]([C:9]([OH:11])=[O:10])=[CH:3][C:2]=1[I:12].CCCCCCCCCC(C)C.C1(C)C=CC=CC=1>>[CH:1]1[C:6]([I:7])=[C:5]([I:8])[C:4]([C:9]([OH:11])=[O:10])=[CH:3][C:2]=1[I:12]Participants
3
Procedure
13 mL of TIBA/isododecane solution (90 g/L) were mixed with 2.5 mL of MAO/toluene solution (Albemarle 30% wt/wt, d=0.928 g/mL, 11.8 mmol MAO) to obtain a MAO/TIBA molar ratio of 2:1. The solution was stirred for 1 h at room temperature and transferred into a 50 mL Schlenk flask containing C-2 (24.2 mg, 29.5 μmol). The final solution was diluted with 22.1 mL of cyclohexane to form a dark orange/red solution after overnight stirring at room temperature (final concentration=50 gTOT/L and 0.645 gmetallocene/L).
Sources & evidence
- ORD record
- ord-5f2006d745794e71a94a114635756466
- Source dataset
- uspto-grants-2010_11
- Patent number
- US07834205B2
Reaction notes
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