TIBA isododecane → 2,3,5-Triiodobenzoic acid

HRID 1174086Notes

Reaction equation

HRID 1174086 reaction equation
[CH:1]1[C:6]([I:7])=[C:5]([I:8])[C:4]([C:9]([OH:11])=[O:10])=[CH:3][C:2]=1[I:12].CCCCCCCCCC(C)C>C1(C)C=CC=CC=1>[CH:1]1[C:6]([I:7])=[C:5]([I:8])[C:4]([C:9]([OH:11])=[O:10])=[CH:3][C:2]=1[I:12]

Participants

3

Reactant 1

HCID 131728349TIBA isododecane

Product 1

HCID 69482,3,5-Triiodobenzoic acid

Reagents, catalysts & solvents 1

HCID 1140TolueneSolvent

Procedure

19.6 mL of TIBA/isododecane solution (110 g/L) were mixed with 4.5 mL of MAO/toluene solution (Albemarle 30% wt/wt, d=0.928 g/mL) to obtain a MAO/TIBA molar ratio of 2:1. The solution was stirred for 1 h at room temperature and transferred into a 50 mL Schlenk flask containing C-3 (33.9 mg, 40.8 μmol). The resulting mixture was diluted with 25.2 mL of isododecane to give a bright orange solution. Final concentration: 70 gTOT/L and 0.686 gmetallocene/L.

Sources & evidence

ORD record
ord-1dce735d46e94e41953b99e822f45a9b
Source dataset
uspto-grants-2010_11
Patent number
US07834205B2

Reaction notes

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