Propylene → HCID 22386386, compound

Participants

Reaction Steps

The amount of 1-hexene reported in table 1 was injected in the autoclave that was then thermostated at the polymerization temperature (90° C.). The solution containing the catalyst/cocatalyst mixture containing the amount of metallocene compound reported in table 1 was injected in the autoclave by syringe at 1 bar of pressure of monomer then the pressure was increased at 7 bar-g of propylene, and the polymerization carried out at constant temperature for the time indicated in table 1. Then stirring was interrupted, the pressure was released to ambient pressure, and the autoclave was opened. At r.t. the solution mixture was discharged into a beaker containing acetone. The polymer was isolated by filtration and then dried in an oven under reduced pressure at 70° C. The polymerization conditions are reported in table 4 and the polymerization results are reported in table 5.

Provenance & Evidence