Participants
| Role | Name | HCID | Charge |
|---|
| Reactant | Azobisisobutyronitrile | HCID 6547 | — |
| Reactant | 2-(2-Ethoxyethoxy)ethyl PROP-2-enoate | HCID 81766 | — |
| Solvent | Toluene | HCID 1140 | — |
| Product | Butyl Acrylate | HCID 8846 | — |
Reaction Steps
A solution of 39.2 g (0.208 mol) of di(ethylene glycol) ethyl ether acrylate and 916 mg (0.0056 mol) of AIBN in 100 ml of dry toluene is degassed by purging with argon for 3 hours. This solution was added to the above solution [Example 3a] by syringe. The mixture is stirred at 60° C. under argon for 48 hours. The solvent is removed by evaporation under vacuum. (viscous yellow oil; 1H NMR: total conversion ˜100%; GPC: not available due to incomplete solubility in THF).
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|
| Patent number | US07837899B2 |
|---|
| Source dataset | uspto-grants-2010_11 |
|---|
| ORD ID | ord-ed4fcb3fa1954a9a9eba2b9ffb5d6d45 |
|---|
| Source note | uspto-grants-2010_11 |
|---|
